کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5438403 | 1398183 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation, sintering and electrochemical performance of novel Fe2N-TiN nanocomposites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Transition metal nitrides (TMNs) hold great promises as electrode materials in energy devices like supercapacitors, lithium ion batteries and solar cells. However, the poor electrochemical stability severely limits their real-life applications. In this study, we prepared electrochemically stable Fe2N-TiN nanocomposite with varied TiN contents by the nitridation of oxide precursors by ammonia. The formation mechanism consists of the solid reaction between TiO2 and Fe2O3. A protective sintering (PS) technique has been developed for the first time to fabricate pure Fe2N-TiN nanocomposite ceramics after comparing different sintering methods including spark plasma sintering (SPS). Porous microstructures formed by homogenous distribution of ultrafine TiN nanoparticles within large Fe2N micro-grains skeleton were obtained after sintering. The electrochemical performances of the Fe2N-TiN nanocomposites by PS have been investigated in different electrolytes. The mechanism of charge storage is mainly due to the double layer capacitance. The composites with 15Â wt% TiN loading show the highest specific capacitance of 58.4Â FÂ gâ1 in 7.5Â M KOH. Furthermore, excellent cycling stability with zero degradation after 1000 cycles was proved for such nanocomposite electrodes, confirming their potential for energy storage.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 12, 15 August 2017, Pages 9226-9234
Journal: Ceramics International - Volume 43, Issue 12, 15 August 2017, Pages 9226-9234
نویسندگان
Linqin Jiang, Lingyan Lin, Fengpo Yan, Baodian Fan, Yiting Chen, Yu Qiu,