کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5458772 | 1516167 | 2017 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In situ synthesis of ultrasmall SnO2 quantum dots on nitrogen-doped reduced graphene oxide composite as high performance anode material for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
SnO2 is considered as one of the anode material for Li-ion batteries in terms of its superiority in high theoretical capacity (1494 mAh gâ1), low cost and environmental friendly. However, it is suffered from several issues such as rapid capacity deterioration, undesirable aggregation of tin particles and pesky expansion of volume. To conquer these shortcomings, a novel composite of ultrasmall SnO2 quantum dots with an average particle size of 4-5 nm anchored on nitrogen-doped reduced graphene oxide (SnO2@NRGO) was first in situ synthesized By means of hydrothermal method. The results show that as-prepared SnO2@NRGO electrode exhibits a greater enhancement in its initial discharge capacity (1678.4 mAh gâ1) and reversible capacity (1333.5 mAh gâ1 after 450 cycles) at a current density of 500 mA gâ1, implying a long cycle life. Furthermore, the high rate capability of SnO2@NRGO is superior to SnO2@RGO and SnO2 electrodes. The excellent electrochemical reversibility of SnO2@NRGO electrode can be ascribed to the great conductivity, ultrahigh specific surface area and the synergetic effect between ultrasmall SnO2 quantum dots and NRGO.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 727, 15 December 2017, Pages 1-7
Journal: Journal of Alloys and Compounds - Volume 727, 15 December 2017, Pages 1-7
نویسندگان
Wei Zhang, Meng Li, Xuezhang Xiao, Xu Huang, Yiqun Jiang, Xiulin Fan, Lixin Chen,