کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5458903 1516178 2017 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Neutron diffraction study of superconducting La3Ni2B112N3−δ
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Neutron diffraction study of superconducting La3Ni2B112N3−δ
چکیده انگلیسی
We have studied structural properties of La3Ni2B2N3−δ samples with distinctly different values of the superconducting transition temperature by means of powder neutron diffractometry and specific heat measurements. The refinement of lattice site occupations reveals full occupations for all sites in the La3Ni2B112N3 structure with space group I4/mmm except for nitrogen site N(2). For samples with Tc = 13.0 K and 13.7 K we obtain for the N(2) site distinctly different occupation factors of 0.90 and 0.93, respectively. The latter confirms a direct relation between the nitrogen stoichiometry and the superconducting transition temperature. Based on the analysis of temperature dependent lattice parameters, atomic displacement factors, lattice heat capacity data and ab initio phonon density of states calculations we discuss the thermal expansion and vibrational properties of superconducting La3Ni2B2N3−δ.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 716, 5 September 2017, Pages 251-258
نویسندگان
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