Micro-crystallization and spectroscopic properties of Er, Yb:RAl-borates (R=Y, Gd) obtained in RAl3(BO3)4-K2Mo3O10-B2O3-R2O3 and RAl3(BO3)4-B2O3 systems

The spontaneous YAl3(BO3)4 (YAB) and GdAl3(BO3)4 (GdAB) crystals (of nominal composition and co-doped with Er and Yb) up to 4-5 mm in length were grown from high-temperature solutions using K2Mo3O10 based fluxes in the temperature range of 1120-900 °C. Glass-ceramic composites based on the YAB and GdAB micro-crystals have been prepared by quenching YAB-B2O3 and GdAB-B2O3 melts and characterized by X-ray diffraction and spectroscopic methods. The vitrified melt was shown to contain micro- and nano-crystalline rare-earth borate phases. Their distribution over the composites has been investigated by electron microscopy and three-dimensional X-ray tomography. The absorption spectra of these materials co-doped with erbium and ytterbium as well as luminescence spectrum were demonstrated.