کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
584126 | 1453179 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Recovery of ammonium alum from waste solutions with a varying ratio of NH4 to Al in groundwater remediation after underground uranium leaching
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Recovery of ammonium alum from waste solutions with a varying ratio of NH4 to Al in groundwater remediation after underground uranium leaching Recovery of ammonium alum from waste solutions with a varying ratio of NH4 to Al in groundwater remediation after underground uranium leaching](/preview/png/584126.png)
چکیده انگلیسی
Experiments with cooling crystallization of ammonium alum, (NH4Al(SO4)2·12H2O), were performed with concentrated multicomponent acidic solutions (originating from underground uranium leaching in Stráž pod Ralskem area, Czech Republic, and containing as the principal components Al3+, NH4+, and SO42âions) as well as with similar solutions prepared in the laboratory. The yield of NH4Al(SO4)2·12H2O crystals increased significantly with the increasing NH4+/Al3+ molar ratio, in accordance with pertinent solubility data. The purifying effect of crystallization was quantified by means of the distribution coefficients, characterizing the uptake of ionic impurities to alum crystals; the tendency of cationic impurities to crystallize with NH4Al(SO4)2·12H2O decreased in the following order: K+ â«Â Cr3+ > Na+ â Fe3+ > Mg2+ â Zn2+ > Fe2+. Additionally, gypsum (CaSO4·2H2O) solubilities at 25 °C, in mother liquors after NH4Al(SO4)2·12H2O crystallization, were determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 147, Issues 1â2, 17 August 2007, Pages 342-349
Journal: Journal of Hazardous Materials - Volume 147, Issues 1â2, 17 August 2007, Pages 342-349
نویسندگان
V. Hostomská, J. Hostomský,