Lumped kinetics for supercritical water oxidation of oily sludge

Oxidation of oily sludge in supercritical water was studied in batch reactor under the conditions of reaction temperature from 390 to 450 °C, pressure up to 25 MPa, and time from 1 to 10 min. The oily sludge oxidation undergoes a parallel-consecutive reaction pathways, in which it first decomposes to intermediates of aliphatic ketones, aldehydes and carboxylic acids with conjugated double bonds and via low molecular mass organic acids to the final product carbon dioxide. A 4-lump kinetic model was proposed to describe supercritical water oxidation of oily sludge. The experimental data obtained were used to estimate the six kinetic constants and the corresponding activation energies in the model. The model testing results revealed that the model predictions were in good agreement with the experimental results. The model helps us get good insight into the performance of the batch reactor that would be useful for optimization of supercritical water oxidation of oily sludge.

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► Oxidation of oily sludge in supercritical water.
► 4-Lump kinetic model.
► Six kinetic constants and the corresponding activation energies in the model.
► The model predictions were in good agreement with the experimental results.