کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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594871 | 1453991 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation of low radioactivity spherical silicon oxide powders via chemical-flame spheroidizing process Preparation of low radioactivity spherical silicon oxide powders via chemical-flame spheroidizing process](/preview/png/594871.png)
In this work, a chemical-flame spheroidizing method was proposed to facilely prepare low radioactivity spherical silicon oxide powders. Firstly, the rice husks, composed of silicon oxide frame, were employed as the raw materials to prepare high-purity colloidal silica nanoparticles with the size 24 nm via a simple “pyrolyzation–ashing–dissolvation” process. Then, the silica colloid was further treated by a spraying–drying process to mainly form mushroomhead-shaped silica particles with particle size 0.5–10 μm. Most of the powders were hollow, the thickness of the walls of hollow silicon oxide powders was about 50–100 nm. The surfaces were rough, the powders had poor fluidity and the apparent density was only 0.21 g/cm3. Finally, almost all these submicro and microparticles were densified by an oxygen–acetylene flame spheroidizing process to get low radioactivity spherical silicon oxide powders with the size 0.5–5 μm. The fluidity, the apparent density and the content of U of the as-prepared spherical silicon oxide powders reached 94 s/50 g, 0.721 g/cm3 and 0.05 × 10−9g/g, respectively. Such silicon oxide material originating from rice husks could potentially be used in very large scale integration field.
Low radioactivity spherical silica powders using the rice husk as the raw materials was obtained via a chemical-flame spheroidizing process.Figure optionsDownload as PowerPoint slideHighlights
► Low radioactivity spherical silicon powders was synthesized via a chemical process and then spheroidizationed by oxygen–acetylene flame process. The chemical-flame spheroidizing process is a novel one.
► Low radioactivity spherical silicon powders was obtained using cheap rice husks as the raw materials not expensive ethyl-orthosilicate hydrolysis.
► The as-prepared spherical silicon powders with lower radioactivity and higher apparent density could be used for very large scale integration circuits packaging to replace radioactivity spherical quartz powders and lower apparent density chemical-synthesis of silicon powders.
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 381, Issues 1–3, 20 May 2011, Pages 13–16