Ethanol synthesis from syngas over Rh-based/SiO2 catalysts: A combined experimental and theoretical modeling study

Catalytic conversion of biomass-derived synthesis gas to ethanol and other C2+ oxygenates has received considerable attention recently due to the strong demands for alternative, renewable energy sources. Combining experimental measurements with first-principles-based kinetic modeling, we investigated the reaction kinetics of ethanol synthesis from CO hydrogenation over SiO2 -supported Rh/Mn alloy catalysts. We find that an Mn promoter can exist in a binary alloy with Rh and play a critical role in lowering the CO insertion reaction (CO + CHx (x = 1–3)) barriers thus improving the selectivity toward ethanol and other C2+ oxygenates, although the barrier toward methane formation is unaffected. The postulation of supported Rh/Mn alloy nanoparticle being the active phase is supported by our experimental characterization using X-ray photoelectron spectroscopy, transmission electron microscopy, and X-ray diffraction of practically used Rh/Mn/SiO2 catalysts. First-principles density functional theory (DFT) calculations further confirmed that the binary Rh/Mn alloy is thermodynamically more stable than the mixed metal/metal oxides under the reducing reaction condition. The reaction kinetics of CO hydrogenation to ethanol on the three-dimensional Rh/Mn nanoparticle under experimental operating conditions was studied using kinetic Monte Carlo (KMC) simulations. The simulated reaction kinetics is qualitatively consistent with experimental observations. Finally, the effects of various promoters (M = Ir, Ga, V, Ti, Sc, Ca, and Li) on the CO insertion reaction over Rh/M alloy nanoparticles were investigated using DFT calculations. We found alloying the promoters with the electronegativity difference, Δχ, between the promoter (M) and Rh being 0.7 is the most effective in lowering the barriers of CO insertion reaction, which leads to higher selectivity to ethanol. This conclusion is in excellent accord with the reported catalytic performance of CO hydrogenation over Rh-based catalysts with different promoters. We believe that the electronegativity difference criterion is very useful in improving the catalytic performance using transition metal-based catalysts for ethanol synthesis from CO hydrogenation.

Combining experimental measurements with first-principles-based kinetic Monte Carlo modeling, the reaction kinetics of ethanol synthesis from CO hydrogenation over Rh/Mn/SiO2 catalysts was studied. We find that addition of Mn promoter into Rh-based catalysts can lower CO insertion barriers thus improving the selectivity toward ethanol and other C2+ oxygenates. The effects of various promoters (M = Ir, Ga, V, Ti, Sc, Ca, and Li) on CO insertion step over Rh/M alloy nanoparticles were further investigated, suggesting that alloying the promoter with the electronegativity difference, Δχ = 0.7, between the promoter M and Rh is the most effective in lowering CO insertion barriers which leads to higher selectivity to ethanol.Figure optionsDownload high-quality image (83 K)Download as PowerPoint slide