Catalysts based on platinum–tin and platinum–gallium in close contact for the selective hydrogenation of cinnamaldehyde

Bimetallic platinum–tin and platinum–gallium catalysts supported on carbon nanofibers (CNF) were prepared via reductive deposition precipitation and impregnation. Detailed EXAFS, TEM-EDX and XPS studies showed that reductive deposition precipitation resulted in a close contact of tin with platinum. These bimetallic catalysts displayed an improved selectivity for cinnamaldehyde hydrogenation towards the desired cinnamyl alcohol as compared to the monometallic platinum catalyst and a bimetallic catalyst prepared by impregnation in which such a close interaction was absent. The general applicability of reductive deposition precipitation as synthesis technique was demonstrated using tin and gallium as promoters.

Platinum–tin catalysts were prepared via (A) impregnation and (B) reductive deposition precipitation. Via (A), a PtSn interaction was absent while via (B) close interaction was observed, thereby enhancing catalytic selectivity.Figure optionsDownload high-quality image (35 K)Download as PowerPoint slide