کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
62238 | 47629 | 2009 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Polarity of the acid chain of esters and transesterification activity of acid catalysts Polarity of the acid chain of esters and transesterification activity of acid catalysts](/preview/png/62238.png)
The effect of polarity of the esters on the transesterification reaction rate has been investigated. The effect was studied in homogeneous and heterogeneous catalysts. The polarity of different ethyl alkanoate esters was varied by (i) increasing the number of carbon atoms in the acid alkyl chain of the esters and (ii) introducing Br and hydroxy substituents at the end of the acid chain of ethyl hexanoate. Polarity was determined through the λmaxλmax of the UV–Vis spectrum of the betaine dye dissolved in the investigated esters (ET(30) scale). The transesterification reaction was carried out with methanol and by using sulfuric acid and a Dowex DR2030 sulfonic resin as homogeneous and heterogeneous catalysts, respectively. It was observed that, in addition to steric hindrance, the polarity of the ester chain has an effect on the reaction rate of the heterogeneous acid catalysts. It is proposed that the positive or negative effect of the polarity is due to repulsive or attractive interactions of the ester chain with the polar groups of the resin and/or with the methanol molecules present in the pores. A very positive effect is found in heterogeneous acid catalysis if H-bonds can stabilize the active intermediate participating in the rate determining step. The attractive or repulsive interactions are absent in the homogeneous case.
Ester methanolysis reaction rate on solid acid catalysts is accelerated when the ester has a polar group with capacity to form H-bonds with surface species whereas is rather unaffected when the polar group cannot establish the H-bonds.Figure optionsDownload high-quality image (71 K)Download as PowerPoint slide
Journal: Journal of Catalysis - Volume 262, Issue 1, 15 February 2009, Pages 18–26