کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
63079 47670 2007 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural evolution of H4PVMo11O40⋅xH2O during calcination and isobutane oxidation: New insights into vanadium sites by a comprehensive in situ approach
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Structural evolution of H4PVMo11O40⋅xH2O during calcination and isobutane oxidation: New insights into vanadium sites by a comprehensive in situ approach
چکیده انگلیسی

H4PVMo11O40⋅8H2O was studied during thermal activation as well as during isobutane oxidation by simultaneous in situ-EPR/UV–vis/Raman spectroscopy, in situ-FTIR spectroscopy, and quasi-in situ-1H and -51V-MAS-NMR. In as-synthesized form, most V sites are pentavalent, octahedrally coordinated, and located within the intact Keggin anions. Stepwise dehydration in N2 up to 350 °C leads to partial reduction and disintegration of the V sites from the Keggin units, followed by their condensation on the outer surface of the latter in square-pyramidal form. In water-free H4PVMo11O40, only V5+ (not V4+) is stable inside the Keggin unit. Thus, disintegration of V from the latter is favored by its reduction to the tetravalent state and thus depends on the redox properties of the atmosphere. Active sites in isobutane oxidation are most likely composed of single O4V4+/5+O species connected to Mo6+ via oxygen bridges. Partial deactivation occurs by formation of carbon-containing deposits.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 245, Issue 2, 25 January 2007, Pages 369–380
نویسندگان
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