Determination of selected perfluorinated compounds and polyfluoroalkyl phosphate surfactants in human milk

► A suitable method for perfluorinated compounds (PFCs) determination in human milk. ► Matrix complexity explains variability in detecting PFCs in human milk. ► Proposed a method for polyfluorinated disubstituted phosphate surfactants in milk. ► First work on the presence of polyfluorinated disubstituted phosphate in human milk.