Preparation and interface structure study on dual-layer polyvinyl chloride matrix reinforced hollow fiber membranes

Polyvinyl chloride (PVC) matrix reinforced hollow fiber membranes including separation layer and porous supported matrix were fabricated via dry-wet spinning process. The mixtures of PVC or polyvinylidene fluoride (PVDF) polymer solutions were uniformly coated on the homogeneous PVC matrix membrane which was prepared by a melt-spinning method. The influences of pre-wetting solutions and polymer concentration on structure and performance of homogenous-reinforced (HMR) PVC hollow fiber membranes were investigated. Furthermore, the interfacial bonding state of HMR PVC hollow fiber membranes was characterized by an indirect method and comparative analysis. The results showed that a dense interface formed in the HMR PVC hollow fiber membrane between these two layers without pre-wetting process. Compared with the matrix membrane which had a rougher outer surface with obvious big pores, the prepared HMR PVC hollow fiber membrane possessed a dense and smooth outer surface with no obvious big pores. Due to the filling of the pre-wet solutions into the pores in the outer edge of the matrix membrane, the HMR PVC hollow fiber membranes formed porous interface in the coating process which improved its permeability. The HMR PVC hollow fiber membranes had a more favorable interfacial bonding than the heterogeneous-reinforced (HTR) PVDF hollow fiber membranes. The tensile strength of prepared PVC matrix reinforced hollow fiber membranes was higher than 12 MPa but lower than the original PVC hollow fiber matrix membrane.