Influence of Beijing outflow on Volatile Organic Compounds (VOC) observed at a mountain site in North China Plain

In order to elucidate an impact of Beijing outflow on air quality in the mountainous area, measurement campaign was carried out in Mt. Mang, located 40 km north of Beijing in September 2007. Volatile Organic Compounds (VOC) observed at the site were mainly influenced by air masses arriving from urban areas. No significant impact of local emission was found. Correlation plots between selected VOC suggests several major emission sources as internal combustion, industrial emission, and coal, oil and biofuel burning. Air masses were classified into “polluted” (influence of Beijing and its satellite cities) and “clean” air mass by using backward trajectory analysis. Two air mass categories revealed significant different characteristics and mixing ratios. Reaction with OH is a major factor controlling mixing ratio of “clean” air mass while impact of dilution is also play important role on “polluted” air mass. Estimation of photochemical age of “polluted” air mass by assuming “clean” air mass for background mixing ratios reveals an averaged of 1.5-1.8 days.

► Measurement of VOC was carried out at a mountain site in the north of Beijing. ► Impact of air pollutants arriving from Beijing and its satellite cities was elucidated. ► Background mixing ratios and photochemical age of VOC were estimated.