کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
63689 48248 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye
ترجمه فارسی عنوان
سلول سوخت زیستی بر اساس پراکسیداز horseradish بی حرکت شده بر روی سولفید مس به عنوان آند برای رنگ زدایی از رنگ AV109 آنتراکینون
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

The potential application of electrochemically formed copper sulfide as horseradish peroxidase mediator in the enzymatic biofuel cell and anthraquinone AV109 dye as a fuel is investigated. The open circuit voltage of 0.52 V and short circuit current of ∼3.6 µA/cm2 are obtained, with the maximum specific power of ∼1 µW/cm2. The influence of internal resistance of the cell is discussed. Decolorization is investigated under open circuit potentials, and under external load of 3.3 kΩ conditions. In both cases, 40% of decolorization is achieved, but are three times faster under external load conditions. Specific energy during decolorization in such cell is estimated to ∼5 mWh/m2. The possible mechanism of the power generation during decolorization of AV 109 dye is discussed.

Simultaneous electric power generation and decolorization of anthraquinone AV109 dye was achieved in enzymatic biofuel cell consisted of horseradish peroxidase immobilized on copper sulfide as anode, and oxygen reduction from air, on platinum, as cathode.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Energy Chemistry - Volume 25, Issue 3, May 2016, Pages 403–408
نویسندگان
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