کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
63980 | 48263 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preferential oxidation of CO in excess H2 over the CeO2/CuO catalyst: Effect of initial support Preferential oxidation of CO in excess H2 over the CeO2/CuO catalyst: Effect of initial support](/preview/png/63980.png)
Three series of CeO2/CuO samples were prepared by impregnation method and characterized by XRD, N2 adsorption-desorption, temperature-programmed reduction (TPR), XPS and TEM techniques. In comparison with the samples prepared with CuO as initial support, the samples with Cu(OH)2 as initial support have higher reducibilities and smaller relative TPR peak areas, and also larger specific surface areas at calcination temperatures of 400 °C–600 °C. As a result, Cu(OH)2 is better than CuO as initial support for preferential oxidation of CO in excess H2 (CO-PROX). The best catalytic performance was achieved on the sample calcined at 600 °C and with an atomic ratio of Ce/Cu at 40%. XPS analyses indicate that more interface linkages Ce-O-Cu could be formed when it was calcined at 600 °C. And the atomic ratio of Ce/Cu at 40% led to a proper reducibility for the sample as illustrated by the TPR measurements.
The samples with Cu(OH)2 as initial support exhibited higher catalytic activities for CO-PROX due to their higher reducibilities and more interface linkages.Figure optionsDownload as PowerPoint slide
Journal: Journal of Energy Chemistry - Volume 23, Issue 4, July 2014, Pages 475–482