Key factors improving oxygen reduction reaction activity in cobalt nanoparticles modified carbon nanotubes

- CoOx-N nanoparticles loaded on CNTs are prepared by a simple procedure.
- CoOx loading/nanoparticle size affects the electrocatalytic behavior.
- ORR activity is very much influenced by the N content in the electrocatalyst.
- C-N-Co interactions are quite important for the remarkable electrocatalytic activity.
- No significant deactivation is observed after MeOH addition with only 1 wt.% of Co.

Multiwall carbon nanotubes (CNTs) decorated with cobalt oxide (CoOx) nanoparticles (NPs) are prepared in various synthesis conditions to investigate their capability as oxygen reduction reaction (ORR) catalysts for fuel cells in alkaline media. The synthesis conditions include the use of protecting, reducing or complexing agents and heat treatment. Higher ORR activity is possible for smaller size of Co NPs catalysts due to the enlarged interfaces between Co species and CNTs. The addition of polyvinylpyrrolidone (PVP) as protecting agent and NaBH4 during the preparation procedure is necessary for obtaining the highest activity since it favors the formation of lower oxidation states for Co species and the incorporation of N groups which improve ORR activity. CNTs loaded with only 1 wt.% of Co NPs prepared by a facile method using PVP, NaBH4 and subsequent heat treatment at 500 °C under N2 atmosphere, demonstrates both similar catalytic activity and stability than Pt/Vulcan (20 wt.% Pt on Vulcan). The synergic chemical coupling effects between CNTs and CoOx NPs and the presence of carbon material with pyridinic N and quaternary N groups formed from the protecting agent decomposition, seem to be the main factors responsible for the remarkable electrocatalytic activity.

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