کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6454503 1418817 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nickel selenide supported on nickel foam as an efficient and durable non-precious electrocatalyst for the alkaline water electrolysis
ترجمه فارسی عنوان
سلنید نیکل بر روی فوم نیکل به عنوان یک الکتروکاتالیست غیرمخرجی کارآمد و بادوام برای الکترولیز آب قلیایی
کلمات کلیدی
سلنید نیکل، تکامل اکسیژن، فوق العاده با دوام، الکترولیز آب قلیایی، خورشیدی به هیدروژن،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


- 3D-Ni3Se2 porous electrode was prepared using one-step hydrothermal method.
- Explored as a low potential electrocatalyst to drive the oxygen evolution reaction.
- Demonstrated 500 h continuous electrolyzer operation using both non-precious electrodes.
- Solar light assisted water splitting reduces the cost of electricity in H2 generation.

Herein, we describe an in-situ hybridization of Nickel Selenide (Ni3Se2) with a Nickel Foam (NF) current collector as an efficient, ultra-durable electrode for the continuous alkaline water electrolysis. Earth abundant, cost effective, non-precious self-made Ni3Se2/NF electrode delivers an oxygen evolution reaction (OER) overpotential value of 315 mV at a current density of 100 mA cm−2 (versus a reversible hydrogen electrode) in aqueous electrolyte of 1 M KOH. On a static current density of 100 mA cm−2, Ni3Se2/NF electrode shows a good OER stability over 285 h with very small potential loss of 5.5% in alkaline electrolyte. Accordingly, the alkaline water electrolyzer constructed with Ni3Se2/NF (anode) and NiCo2S4/NF (cathode), it requires 1.58 V to deliver 10 mA cm−2 current density, with 500 h continuous operation in 1 M KOH. In addition, we demonstrate that the light-driven water splitting using solar panel, it can be a promising approach to facilitate true independence from electricity in H2 fuel economy. Overall, this methodology is one of the appropriate energy efficient ways to reduce the cost of water splitting devices, as it may simplify the diverse process and equipment.

178

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 203, April 2017, Pages 485-493
نویسندگان
, ,