کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6455182 | 1419023 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Short communicationFunctionalised [(NHC)Pd(allyl)Cl] complexes: Synthesis, immobilisation and application in cross-coupling and dehalogenation reactions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
- A novel [(NHC)PdII] unit has been immobilised on silica coated nanoparticles.
- Good activity shown in Suzuki-Miyaura and chloroarene dehalogenation reactions.
- Pd-mediated transfer hydrogenation of carbonyl compounds is demonstrated
A novel NHC-palladium(II) (NHCÂ =Â N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 87, 5 December 2016, Pages 78-81
Journal: Catalysis Communications - Volume 87, 5 December 2016, Pages 78-81
نویسندگان
John-Michael Collinson, James D.E.T. Wilton-Ely, Silvia DÃez-González,