کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6465124 | 1422951 | 2017 | 11 صفحه PDF | دانلود رایگان |
- A new manner of ZVI based MFC-biosensor was developed for the properties of UASB-MFC biosensor accumulating.
- The electrical signal response and amplified properties were affected by electron transport and pH of system.
- ZVI enhanced the direct interspecies electron transfer through intensified anaerobic digestion.
- The effects of volatile fatty acid component proportion on the exoelectrogen and biosensing activities were revealed.
The development of a convenient and sensitive sensor such as a microbial fuel cell (MFC) to monitor the operation of upflow anaerobic sludge blanket (UASB) is indispensable. However, the biosensor's properties were affected due to excessive acidification and suffocation of the electron transport. In this study, zero-valent iron (ZVI) was applied to restrain excessive acidification and improve the sensing performance. According to the results, the response rate of electrical signal accumulated with the addition of ZVI compared to the control reactor. As well as the electrical signal amplified and the subsidence rate maximum reached 0.059Â V/h with 30Â mg/L ZVI added that 883% higher than the control one during the stage (COD concentration 500Â mg/L-1000Â mg/L). With the electrochemical analysis, the internal resistance of ZVI-UASB-MFC decreased and redox activity promoted effectively with ZVI added. During the overloading phase, the fractional content of butyric acid changed from 53% to 31%, while that of acetic acid rose from 18% to 39% after 30Â mg/L ZVI addition. These results indicated that adding ZVI to the digestion could retard excessive acidification by promoting butyric acid conversion and accumulating direct interspecies electron transfer simultaneous for enhancing the biosensor's performance. According to the Fe2+ and Fe3+ of effluent were 2.25Â mg/L and 0.39Â mg/L with 50Â mg/L ZVI addition, moderate amount of ZVI was effective for system and safety to the environment. It might helpfully provide a promising way to enhance biosensing.
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Journal: Chemical Engineering Journal - Volume 327, 1 November 2017, Pages 1117-1127