کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6466421 | 1422963 | 2017 | 8 صفحه PDF | دانلود رایگان |
- Unique hierarchical mesoporous layered-cube Mn2O3 was prepared.
- As-prepared Mn2O3 displays a good rate performance at 4 A gâ1 (339.7 mA h gâ1).
- At current density of 1 A gâ1, it still keeps 906.8 mA h gâ1 after 100 cycles.
Unique hierarchical mesoporous layered-cube Mn2O3 has been synthesized in dual-solvent by a solvothermal method. The structure and morphology of the as-prepared materials were analyzed by X-ray diffraction and electron microscope. The results show that the as-prepared sample can be indexed as rarely reported orthorhombic Mn2O3 with layered-cube morphology, and the possible formation mechanism is speculated. When evaluated as anode materials, the layered-cube Mn2O3 shows good electrochemical properties with high discharge capacity of 1664.7 mAh gâ1 at 1 A gâ1, maintains capacity of 906.8 mAh gâ1 after 100 cycles. Especially, sample maintains original morphology even at high current density (1 A gâ1) after 100 cycles. The excellent cycle stability and superior rate performance are attributed to hierarchical mesoporous structure in conjunction with its unique layered-cube, which can offer more ions and electrons transporting channels from different directions, provide high interfacial lithium storage and prevent the collapse of structure.
Journal: Chemical Engineering Journal - Volume 315, 1 May 2017, Pages 583-590