کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
64690 | 48366 | 2016 | 8 صفحه PDF | دانلود رایگان |

• Novel bifunctional ionic liquid based PMO supported K2CO3 was prepared and characterized.
• Excellent properties of this nanomaterial were developed in details.
• This material was applied as an efficient nanocatalyst for the Knoevenagel reaction.
• The Knoevenagel products were obtained in high to excellent yields and selectivities.
• This nanocatalyst was reused several times without important decrease in efficiency.
A novel ionic liquid based bifunctional periodic mesoporous organosilica supported potassium carbonate (BPMO-IL-KCO3) is prepared, characterized and its catalytic efficiency is studied in the Knoevenagel reaction. The BPMO-IL-KCO3 was prepared by chemical attachment of 1-methyl-(3-trimethoxysilylpropyl) imidazolium chloride on an ionic liquid based PMO followed by treatment with potassium carbonate under ambient temperature. This material was characterized with thermal gravimetric analysis (TGA), energy-dispersive X-ray (EDX) spectroscopy, powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The BPMO-IL-KCO3 was then successfully applied as efficient base catalyst in the Knoevenagel condensation of different aldehydes with ethyl cyanoacetate and gave high to excellent yields of the corresponding coupling products. The catalyst was recovered and reused several times without significant decrease in activity and selectivity. The recovered catalyst was also analyzed with TEM and nitrogen sorption experiment to investigate structural stability and durability of the material under applied conditions.
A novel ionic liquid based bifunctional periodic mesoporous organosilica supported potassium carbonate was prepared, characterized and its catalytic activity was investigated in the Knoevenagel reaction. This catalyst exhibited high efficiency for the preparation of different derivatives of Knoevenagel products under moderate reaction conditions. Moreover, the catalyst was successfully recovered and reused several times without important decrease in reactivity and stability.Figure optionsDownload high-quality image (230 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 415, 1 May 2016, Pages 74–81