کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6469917 | 1424106 | 2017 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Mesoporous Zn2SnO4 as effective electron transport materials for high-performance perovskite solar cells Mesoporous Zn2SnO4 as effective electron transport materials for high-performance perovskite solar cells](/preview/png/6469917.png)
- Large grain and mesoporous Zn2SnO4 are synthesized by a facile hydrothermal method.
- Perovskite device with Zn2SnO4 electron transport layer get efficiency of 17.21%.
- While the device with TiO2 electron transport layer obtain an efficiency of 14.83%.
- Superior photovoltaic performance stems from the intrinsic characteristics of Zn2SnO4.
Electron transport layer with higher carrier mobility and suitable band gap structure plays a significant role in determining the photovoltaic performance of perovskite solar cells (PSCs). Here, we report a synthesis of high crystalline zinc stannate (Zn2SnO4) by a facile hydrothermal method. The as-synthesized Zn2SnO4 possesses particle size of 20Â nm, large surface area, mesoporous hierarchical structure, and can be used as a promising electron-transport materials to replace the conventional mesoporous TiO2 material. A perovskite solar cell with structure of FTO/blocking layer/Zn2SnO4/CH3NH3PbI3/Spiro-OMeOTAD/Au is fabricated, and the preparation condition is optimized. The champion device based on Zn2SnO4 electron transport material achieves a power conversion efficiency of 17.21%, while the device based on TiO2 electron transport material gets an efficiency of 14.83% under the same experimental conditions. The results render Zn2SnO4 an effective candidate as electron transport material for high performance perovskite solar cells and other devices.
Journal: Electrochimica Acta - Volume 251, 10 October 2017, Pages 307-315