کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6469992 1424106 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Zinc doped H2Ti12O25 Anode and Activated Carbon Cathode for Hybrid Supercapacitor with superior performance
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Zinc doped H2Ti12O25 Anode and Activated Carbon Cathode for Hybrid Supercapacitor with superior performance
چکیده انگلیسی


- Hybrid supercapacitors were fabricated with H2Ti12-xZnxO25-x (x = 0∼0.6) anode.
- Capacitance retention of H2Ti11.7Zn0.3O24.7 was 92% after 1000 cycles.
- Power densities of H2Ti11.7Zn0.3O24.7 were 42.4-8.1 Wh kg-1 from 0.1 to 3 Ag-1.
- Energy densities of H2Ti11.7Zn0.3O24.7 were 182-5676.2 W kg-1 from 0.1 to 3 Ag-1.

Hybrid supercapacitors were fabricated with both pristine and H2Ti12-xZnxO25-x (x = 0.15, 0.3, 0.45, 0.6) anode electrodes. The structural properties and morphology of particles after zinc doping were confirmed by X-ray diffraction (XRD), Rietveld refinement, X-ray photoelectron spectroscopy (XPS), and scanning electron micron microscopy (SEM). The electrochemical performances of the hybrid supercapacitors were measured. The results show that the H2Ti11.7Zn0.3O24.7 not only enhanced discharge specific capacitances of 70.7 Fg−1 at 0.5 Ag−1, but also capacitance retention of 92% after 1000 cycles. In addition, H2Ti11.7Zn0.3O24.7 has lower polarization and charge transfer resistance (Rct) of 0.142 Ω. The power densities and energy densities of H2Ti11.7Zn0.3O24.7 were 42.4-8.1 Wh kg−1 and 182-5676.2 W kg−1 at 0.1 and 3 Ag−1, respectively. Consequentially, Zn doping improved structure stability and electrochemical performance of H2Ti12O25. Therefore, hybrid supercapacitors were fabricated using a H2Ti11.7Zn0.3O24.7 anode can be regarded as energy storage devices.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 251, 10 October 2017, Pages 613-620
نویسندگان
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