کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6470651 | 1424112 | 2017 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In situ growth of single-stranded like poly (o-phenylenediamine) onto graphene for high performance supercapacitors
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Herein, we present the first report on a new strategy to synthesize a kind of stereoregular poly (o-phenylenediamine) (PoPD)-graphene nanocomposite bound only by chemical bond via in situ growth of single-stranded like PoPD onto graphene for high performance supercapacitor. Firstly, aniline groups are grafted onto graphene oxide (GO) surface by diazotization reaction to prepare aniline functionalized graphene oxide (a-GO), and then o-phenylenediamine (oPD) monomers are polymerized on a-GO surface to form PoPD wrapped graphene oxide (a-GO/PoPD). Subsequently, the a-GO/PoPD are washed repeatedly to make the PoPD to anchor with aniline groups (GO-a-PoPD) to stay (due to the solubility of PoPD in aqueous solution), followed by reduction to obtain single-stranded like PoPD anchored graphene (r-GO-a-PoPD). Consequently, the r-GO-a-PoPD nanocomposite with special combining form and structure exhibits a high specific capacitance of 381Â FÂ gâ1 in 1Â M H2SO4 at 1Â AÂ gâ1, and 230Â FÂ gâ1 in 6Â M KOH at 1Â AÂ gâ1. Furthermore, the symmetric supercapacitor exhibits excellent stability, high energy density and power density. The achieved high electrochemical performance is ascribed to the stable connection of PoPD with graphene and the sufficient use of them, which provide high capacitance and stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 245, 10 August 2017, Pages 41-50
Journal: Electrochimica Acta - Volume 245, 10 August 2017, Pages 41-50
نویسندگان
Wenji Yang, Haihui Zhou, Zheng Huang, Huanxin Li, Chaopeng Fu, Liang Chen, Mengbo Li, Shanshan Liu, Yafei Kuang,