کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6470704 | 1424112 | 2017 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Nitrogen-doped hierarchical carbon spheres derived from MnO2-templated spherical polypyrrole as excellent high rate anode of Li-ion batteries Nitrogen-doped hierarchical carbon spheres derived from MnO2-templated spherical polypyrrole as excellent high rate anode of Li-ion batteries](/preview/png/6470704.png)
Hierarchical nitrogen-doped carbon spheres (NCSs) prepared by annealing the MnO2-templated spherical polypyrrole (PPy) at 450 or 600 °C were tested as anode materials of Li-ion batteries. The NCSs annealed at 450 °C exhibited higher nitrogen content, more amorphous carbon structure, and lower surface area as compared to the sample annealed at 600 °C. The specific capacities and rate performances of both NCSs samples were much higher than that of commercial mesocarbon microbeads (MCMBs). The NCSs annealed at 600 °C exhibited higher capacity at low current density (<0.5 A gâ1) but more rapid capacity decay at elevated current rates referring to the sample annealed at 450 °C. The NCSs annealed at higher temperature also possessed inferior cycling stability, possibly due to its lower electronic conductivity and higher degree of graphitization. A high specific capacity of 250.8 mAh gâ1 was achieved on the NCSs annealed at 450 °C at 3 A gâ1, demonstrating their high potentiality as anode of high power Li-ion batteries.
Journal: Electrochimica Acta - Volume 245, 10 August 2017, Pages 279-286