کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6470873 1424112 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Highly stable three-dimensional nickel-iron oxyhydroxide catalysts for oxygen evolution reaction at high current densities
ترجمه فارسی عنوان
کاتالیزور اکسید هیدروکسید نیکل آهن سه بعدی بسیار مقاوم در برابر واکنش تکامل اکسیژن در تراکم های جاری بالا
کلمات کلیدی
تقسیم آب، الکترو کاتالیزورها، الکترود سه بعدی، اکسید هیدروکسید نیکل آهن
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


- 3D self-supported Ni1-x-FexOOH/carbon fiber cloth (CFC) electrodes are synthesized.
- The electrodes exhibit remarkably enhanced OER activities as x = 0.30.
- The self-supported electrode requires an overpotential of 205 mV at 200 mA cm−2.
- The electrode can operate stably at >350 mA cm−2 over 100 hours.
- The OER performance of the electrode outperforms the commercial IrO2 catalyst.

Design of low-cost and highly efficient electrodes for oxygen evolution is highly desirable for bulk water electrolysis associated with several conversion and storage of the renewable energies. Mixed Ni-Fe catalysts have showed excellent activities towards oxygen evolution reaction (OER), however, the long-term stability at high current densities has not been well-documented. Here we fabricate three-dimensional (3D) self-supported Ni1-x-FexOOH/carbon fiber cloth (CFC) electrodes for highly efficient oxygen evolution through in situ electrochemical activation of the corresponding 3D Ni1-x-FexS/CFC precursors. The activated Ni-Fe electrodes exhibit remarkably enhanced OER activities compared to the pure Ni and Fe catalysts and the highest OER activity is achieved as x = 0.30. To drive current densities of 100 and 200 mA cm−2, the 3D Ni0.70Fe0.30OOH/CFC electrode in 1.0 M KOH only requires overpotentials of 200 and 205 mV, respectively, outperforming the commercial IrO2 catalyst and all previously reported Ni-Fe catalysts. Furthermore, the Ni0.70Fe0.30OOH/CFC electrode can continuously operate at >350 mA cm−2 over 100 hours with a negligible current loss in 1.0 M KOH. Such excellent activity and robust long-term stability at high current density demonstrate that the 3D Ni-Fe catalysts can applied in industry for large-scale oxygen production.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 245, 10 August 2017, Pages 770-779
نویسندگان
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