کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6471043 | 1424110 | 2017 | 11 صفحه PDF | دانلود رایگان |
A novel polyprrole (PPy)-decorated hierarchical NiCo2O4 nanoneedles was grown on highly conductive carbon fiber paper (CFP) for high performance asymmetric supercapacitor applications. The PPy-decorated hierarchical NiCo2O4 nanoneedle on CFP (PPy-NiCo2O4@CPF) was grown by two steps. At first, NiCo2O4 nanoneedle was grown by hydrothermal process and followed by the deposition of PPy through electrochemical method. The fabricated PPy-NiCo2O4@CPF electrode displayed the higher electrochemical performance. The specific capacitance was â¼910 F g-1 at a current density of 1 A gâ1 and cyclic stability was â¼88% after 10,000 cycles. To explore real performance of the electrode, we have fabricated solid state asymmetric supercapacitor using PPy-NiCo2O4@CFP as positive and nitrogen doped reduced graphene oxide (N-rGO) as negative electrodes. The fabricated asymmetric device delivered a specific capacitance of 118.6 F g-1 at a current density of 1.0 A gâ1 with a maximum energy density of 40.81 Wh Kgâ1 (at a power density of 738.27 W Kgâ1) and maximum power density of 3746.77 W Kgâ1 (at an energy density of 13.53 Wh Kgâ1). The impressive results suggest that flexible PPy-NiCo2O4@CFPs can be a promising electrode material for supercapacitor applications.
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Journal: Electrochimica Acta - Volume 247, 1 September 2017, Pages 524-534