کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6471397 | 1424124 | 2017 | 13 صفحه PDF | دانلود رایگان |

The effect of boiling bubbles on the passivation degradation of Alloy 800 in thiosulphate-containing aqueous electrolyte was experimentally investigated using corrosion potential, anodic polarization, combined with Secondary Ion Mass Spectrometry (SIMS) and X-ray Photoelectron Spectroscopy (XPS). The results showed that the boiling bubbles decreased the pitting potential by enhancing the mass transport. The specimen immersed in boiling electrolyte have a thicker anodic film and a greater amount of sulfur incorporation into the passive layer compared with the experiments at 99 °C. Moreover, a higher ratio of low valance sulfur species was detected on the specimen in boiling test electrolyte, indicating that the boiling bubbles reduced the corrosion resistance of Alloy 800.
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Journal: Electrochimica Acta - Volume 233, 10 April 2017, Pages 13-25