کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6471529 | 1424122 | 2017 | 10 صفحه PDF | دانلود رایگان |

A novel ternary rGO/PPy/S nanocomposite possessing of a hierarchical nanostructure via incorporating the matrix of reduced graphene oxide (rGO) coated by polypyrrole (PPy) with sulphur was prepared by a facile one-pot in situ method. The chemical bonds exist between PPy and rGO through the formation of graphitic N and pyridine oxide N, and the CS, SC = S and SO chemical bonds form between rGO/PPy and S in the structure of the rGO/PPy/S material. The loading content of sulphur is 69.43 wt.% for the rGO/PPy/S sample. The rGO/PPy/S material exhibits a high performance when used as the cathode of Li-S battery. The initial and last discharge capacity arrived at 991.5 and 626.7 mAh gâ1 at 1C with 400 cycles which is corresponding to the capacity retention ratio of 63.2%, indicating its very high cyclic stability. The discharge capacity of 537.4 mAh gâ1 could be obtained at 5C and it maintained at 442.1 mAh gâ1 after 400 cycles with the Coulombic efficiency of more than 90%, showing its excellent rate stability.
Journal: Electrochimica Acta - Volume 235, 1 May 2017, Pages 32-41