کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6471537 | 1424122 | 2017 | 10 صفحه PDF | دانلود رایگان |
- One-pot glycine-nitrate solution combustion synthesis was employed.
- High performance FeOx/carbon/graphene composite was prepared.
- The composite showed high discharge capacity 834 mAh gâ1 after 100 cycles.
- The composite displayed high rate capability.
Iron oxide has been considered as one of the most promising anode materials due to its high theoretical capacity, low cost and environmental friendliness. However, few simple and effective method is explored for preparing iron oxides with high electrochemical performance via alleviating the volume change and agglomeration of active particles. In this work, FeOx/carbon/graphene composites are fabricated by a facile solution combustion synthesis within several minutes in one step. Characterization demonstrates that FeOx nanoparticles are well-dispersed in the graphene matrix. The presence of graphene effectively alleviates the agglomeration of FeOx nanoparticles, and accommodates the volume changes during the cycling process, thereby resulting in the excellent electrochemical performance. FeOx/carbon/graphene (31.4 wt.% graphene) delivers a higher discharge capacity of 824 mAh gâ1 after 100 cycles at 0.4 A gâ1, in comparison to the value of 301 mAh gâ1 for the composite without graphene. This easily prepared FeOx/carbon/graphene composite with excellent electrochemical performance can be considered as one promising anode material used for lithium-ion batteries.
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Journal: Electrochimica Acta - Volume 235, 1 May 2017, Pages 88-97