کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6471749 | 1424122 | 2017 | 11 صفحه PDF | دانلود رایگان |

In present work, we prepared nitrogen doped graphene oxide (N-GO) by using 1,3-xylenediamine (XDA) as nitrogen precursor which was further decorated with Co(OH)2 nanoflower. The physiochemical analysis such as X-ray photoelectron spectroscopy and scanning electron microscopy revealed the successful doping of nitrogen on GO and fine dispersion of Co(OH)2 nanoflower on the surface of N-GO. The as prepared N-GO-Co(OH)2 was electrochemically reduced (N-rGO-Co(OH)2) to precisely adjust its electrochemical properties. The N-rGO-Co(OH)2 was used as a novel electrode modifier for the simultaneous detection of dopamine (DA) and uric acid (UA). From the combined effects of N-doping and excellent electrocatalytic properties of the Co(OH)2 nanoflower, constructed sensor exhibited high electrochemical sensing activity with the wide linear response, limit of detection and limit of quantification of 1.0Â ÃÂ 10â8Â M and 3.0Â ÃÂ 10â8Â M for DA and 1.0Â ÃÂ 10â7Â M and 3.6Â ÃÂ 10â7Â M for UA respectively. The N-rGO-Co(OH)2 nanocomposite showed long-term sensing stability, reproducibility and excellent analytical response in urine for DA and UA detection. Furthermore, N-rGO-Co(OH)2 also revealed remarkable anti-interfering behavior towards other biomolecules including ascorbic acid (AA), serotonin (5-HT) and glucose (Glu). The N-rGO-Co(OH)2 nanocomposite manifests intriguing application potential as the candidate for the application of the electrochemical sensor for simultaneous detection of DA and UA.
Journal: Electrochimica Acta - Volume 235, 1 May 2017, Pages 709-719