کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6471797 | 1424125 | 2017 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Ba0.9La0.1Li2Ti6O14: Advanced lithium storage material for lithium-ion batteries Ba0.9La0.1Li2Ti6O14: Advanced lithium storage material for lithium-ion batteries](/preview/png/6471797.png)
- Ba-site substituted Ba0.9M0.1Li2Ti6O14 is prepared as lithium host anode material.
- K, Zn and La are used as Ba-site dopants for BaLi2Ti6O14.
- Ba0.9La0.1Li2Ti6O14 displays enhanced lithium storage capability.
- Structural stability and reversibility of Ba0.9La0.1Li2Ti6O14 are studied.
- In-situ XRD investigation is performed to study the lithium storage process.
Metal doping is an effective way to improve the electrochemical properties of titanates. In this work, Ba-site substituted Ba0.9M0.1Li2Ti6O14 (M = K, Zn, La) are synthesized to fabricate high performance titanate anode for lithium-ion batteries. Electrochemical evaluations reveal that introducing metal doping at Ba-site can result in higher ionic/electronic conductivity. As a result, Ba0.9M0.1Li2Ti6O14 exhibits enhanced lithium storage capability. Especially for Ba0.9La0.1Li2Ti6O14, it shows the best electrochemical performance with a high reversible charge capacity of 151.3 mAh gâ1 and high capacity retention of 94.21% at a current density of 100 mA gâ1. For comparison, the pristine BaLi2Ti6O14 only exhibits a reversible charge capacity of 128.5 mAh gâ1 with the capacity retention of 80.06% after 100 cycles. Further, the lithium storage process is investigated in detail by in-situ structural observation, which reveals a maximum volume expansion of 1.9% for Ba0.9La0.1Li2Ti6O14 during charge-discharge cycle. It shows that Ba0.9La0.1Li2Ti6O14 is a possible material with high structural reversibility for lithium storage.
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Journal: Electrochimica Acta - Volume 232, 1 April 2017, Pages 132-141