کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472099 1424126 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure evolutions and high electrochemical performances of carbon aerogels prepared from the pyrolysis of phenolic resin gels containing ZnCl2
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Structure evolutions and high electrochemical performances of carbon aerogels prepared from the pyrolysis of phenolic resin gels containing ZnCl2
چکیده انگلیسی


- The carbonization and activation of carbon aerogels can be carried out in one step by the pyrolysis of phenolic resin gels containing ZnCl2.
- Structures of carbon aerogels can be handily and effectively adjusted by changing the content of ZnCl2 in phenolic resin gels under the same heating condition.
- High electrochemical performances of carbon aerogels at large charge-discharge current densities are resulted from their structure adjustment.

Carbon aerogels (CAs) were prepared via the pyrolysis of phenolic resin gels (PRGs) containing ZnCl2. The pyrolysis of PRGs and the activation of resulted amorphous carbons in CAs can be carried out in one step. Structure characterizations of CAs were performed by X-ray diffraction, Raman spectrum and gas adsorption-desorption method. Electrochemical performances of CAs were investigated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. CAs with specific surface area of 2846 m2 g−1 can display its specific capacitance of 246 F g−1 at 1 A g−1 and 219 F g−1 at 10 A g−1. The addition of ZnCl2 in matrix of PRGs by a hydrothermal treatment can effectively avoid its serious volatilization at higher temperatures and enhance its activation efficiency. A series of structure evolutions in CAs including their specific surface areas, pore volumes and accumulation states of laminar carbon molecules can be caused by changing the content of ZnCl2 in PRGs. High electrochemical performances of CAs are resulted from their adjusted carbon structures. The relation between the structure evolutions in CAs and their improved electrochemical performances is also discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 231, 20 March 2017, Pages 601-608
نویسندگان
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