کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6472177 | 1424130 | 2017 | 8 صفحه PDF | دانلود رایگان |
In this work, a highly sensitive enzyme- and metal-free electrochemical method for superoxide anion (O2â) detection has been developed by employing screen-printed carbon electrodes (SPCE) modified by nitrogen doped hollow mesoporous carbon spheres (N-HMCS). For comparison, solid carbon spheres (SCS) and hollow mesoporous carbon spheres (HMCS) were also synthesized to fabricate the modified SPCE. Compared with SCS/SPCE and HMCS/SPCE, N-HMCS/SPCE displayed a higher electrochemical performance. When applied for electrochemical detection of O2â, N-HMCS/SPCE exhibited a high sensitivity of 1.49 μA cmâ2 μMâ1, better than SCS/SPCE and HMCS/SPCE and many of enzyme- or metal-based superoxide anion sensors. N-HMCS is expected to become a new generation of sensing materials for electrochemical analysis of O2â.
A highly sensitive enzyme- and metal-free electrochemical sensor for superoxide anion (O2â) detection has been developed based on nitrogen doped hollow mesoporous carbon spheres (N-HMCS) modified screen-printed carbon electrodes (N-HMCS/SPCE).126
Journal: Electrochimica Acta - Volume 227, 10 February 2017, Pages 69-76