کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6472182 | 1424130 | 2017 | 6 صفحه PDF | دانلود رایگان |
One of the primary obstacles to the commercialization of dye-sensitized solar cells (DSSCs) is the improvement of their long-term stability. Here, we report greatly improved long-term stability of DSSCs, which have PEDOT:FTS polymer as a counter electrode. DSSCs with this PEDOT:FTS film demonstrate slightly lower power conversion efficiency of 8.1% under standard conditions (AM 1.5Â G, 100Â mWcmâ2) compared to the â¼9.1% efficiency of Pt, using an electrolyte with iodine/iodide, which is the most popular redox shuttle. However, we demonstrate that this conducting polymer counter electrode facilitates the fabrication of solar cells with greatly improved long-term stability compared to Pt-based ones after exposure to electrolyte soaking conditions. Various electrochemical analyses were performed to evaluate the enhanced durability of PEDOT:FTS polymer in the highly corrosive iodine/iodide electrolyte under a continuous redox reaction condition.
Journal: Electrochimica Acta - Volume 227, 10 February 2017, Pages 95-100