کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6472261 | 1424130 | 2017 | 7 صفحه PDF | دانلود رایگان |

- A novel h-BN-doped PVA-H2SO4 GPE is first fabricated using a facile method.
- The novel GPE exhibits a dramatically enhanced ionic conductivity.
- The h-BN nanosheets act as a super-highway for ion conducting.
A novel hexagonal boron nitride nanosheets (h-BN)-doped poly (vinyl alcohol)-sulfuric acid (PVA-H2SO4) gel polymer electrolyte (GPE) is first fabricated through a facile freeze-thaw method. The ionic conductivities of the h-BN-doped PVA-H2SO4 GPEs with various h-BN nanosheet contents are evaluated. With the optimal content of h-BN nanosheets (0.025 mg mlâ1), the ionic conductivity of the GPE can reach up to 29 mS cmâ1, three times higher than that of GPE without the h-BN nanosheets (9 mS cmâ1). The h-BN nanosheets are considered as a “super-highway” for ion transport in PVA-H2SO4 GPE. Moreover, a symmetric qusai-solid-state supercapacitor, with activated carbon as electrodes and the h-BN nanosheets-doped PVA-H2SO4 gel polymer as an electrolyte and separator, delivers a high specific capacitance, good rate capability, and excellent cycle stability. At the current density of 0.5 A gâ1, the symmetry qusai-solid-state supercapacitor can deliver an electrode specific capacitance of 124.5 F gâ1, and remain 99.2% capacitance after 5000 charge-discharge cycles. The h-BN nanosheets-doped GPE, with superior performance and facile synthesis method, appears to be a promising candidate for high-performance qusai-solid-state supercapacitors and other electrochemical devices, such as rechargeable batteries, fuel cells. This work also sheds light on the possibility to use 2D materials in advanced GPE.
Journal: Electrochimica Acta - Volume 227, 10 February 2017, Pages 455-461