کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472279 1424137 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nitrogen-doped graphene supported palladium-nickel nanoparticles with enhanced catalytic performance for formic acid oxidation
ترجمه فارسی عنوان
گرافن دوتایی نیتروژن از نانوذرات پالادیوم نیکل پشتیبانی می کند با عملکرد کاتالیزوری افزایش یافته برای اکسیداسیون اسید فرمیک
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

Nitrogen-doped graphene (NG) supported palladium-nickel nanoparticles with uniform dispersion are synthesized as catalysts for the electro-oxidation of formic acid. The catalysts are characterized by X-ray powder diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS). Our TEM results show that the Pd/Ni nanoparticles on NG are uniform with narrower size distribution than those on native graphene. XPS analysis reveals that Pd/NG and 1Pd1Ni/NG systems have more Pd0 and less Pd2+ content in comparison with the Pd/G and 1Pd1Ni/G counterparts respectively. This difference might be caused by the electron-donating effects of nitrogen species on the graphene surface. In addition, the electrochemical results show significantly enhanced catalytic activity and stability of 1Pd1Ni/NG as the catalyst for the formic acid oxidation reaction. The enhanced activity is not only attributed to the better uniform dispersion of nanoparticles and the enhanced electronic effect between metal particles and the support, but also ascribed to the synergistic effect of Ni incorporation to Pd.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 83-90
نویسندگان
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