کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6472460 | 1424137 | 2016 | 11 صفحه PDF | دانلود رایگان |

- A series of metal oxide double layer nanospheres were prepared.
- The obtained materials show excellent performances in lithium ion batteries and supercapacitors.
- The unique structure of double layers is beneficial for superior electrochemical performances.
In this work, a series of metal oxide double-layer nanospheres (DLNs), such as Mn2O3, Co3O4, NiO, NiCo2O4, and MnCo2O4 have been successfully synthesized through a general template method. The layers of nanospheres were assembled by different nanostructure units and the removing of the SiO2 template formed a void of several ten nanometers between the double layers, resulting large specific surface areas for them. The energy storage performances of the as-prepared double-layer nanospheres were further investigated in lithium ion battery and supercapacitor systems. Based on their unique nanostructures, the double-layer nanospheres exhibit excellent electrochemical performance with long cycle stability and high specific capacities or capacitances. The best of these, DLNs-NiCo2O4 can deliver a reversible capacity of 1107 mAh gâ1 at 0.25C after 200 cycles in lithium ion battery system, and shows a capacitance of 1088 F gâ1 with capacitance loss of less than 3% at 5 A gâ1 after 5000 cycles in supercapacitors.
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 643-653