کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6472594 | 1424135 | 2016 | 7 صفحه PDF | دانلود رایگان |
The polyoxometalate [PMo11O39]7â was synthesized and used as catalyst for the reduction of nitrite ions. This mono-lacunary keggin anion, cited as PMo11, was confined within a matrix of either oxidized single-walled carbon nanotubes (ox-SWCNTs) or reduced graphene oxide (rGO) on glassy carbon (GC) electrodes to improve the electron transfers. Five different configurations were characterized using cyclic voltammetry and evaluated in an amperometric sensor setup for nitrite detection where the amount of the different components were optimized. The configuration using only ox-SWCNTs and PMo11 on GCE showed best sensitivities of up to 44.41 mA Lmolâ1 and a satisfying reproducibility (RSD: â¼2.64% for four identic electrodes). Furthermore, a linear range between 3.0 Ã 10â5 mol Lâ1 and 1.6 Ã 10â2 mol Lâ1 with a detection limit of 3.0 Ã 10â5 mol Lâ1 was obtained. The final sensor setup also showed good selectivity towards interfering ions.
The polyoxometalate [PMo11O39]7â confined in nanostructured carbon matrices was evaluated as catalyst for the selective electrochemical detection of nitrite ions.146
Journal: Electrochimica Acta - Volume 222, 20 December 2016, Pages 402-408