کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6472608 | 1424135 | 2016 | 8 صفحه PDF | دانلود رایگان |
- The solvothermally synthesized mesoporous Ni-P nanocatalysts were used for alkaline urea electrooxidation.
- The Ni-P nanocatalysts exhibited higher activity and stability than the Ni nanocatalysts.
- The structural effect of porous nanowire surface led to the superior activity.
- The electronic effect between Ni and P resulted in the enhanced stability.
Mesoporous nickel phosphide (Ni-P) nanocatalysts have been synthesized via a facile solvothermal strategy and used for urea electrooxidation in alkaline medium. The physicochemical properties and electrocatalytic performances have been investigated. Due to the structural effect and electronic effect, the Ni-P nanocatalysts achieve a lower overpotential, higher activity and better stability compared with the Ni nanocatalysts. Therefore, an onset oxidation potential of 1.37Â V (vs. RHE), a peak current density of 70Â mAÂ cmâ2 and a good current retention of 58% for 1000Â s at 1.52Â V have been achieved by the Ni-P nanocatalysts, which show enhanced performance compared to the Ni nanocatalysts (1.42Â V, 62Â mAÂ cmâ2, 39% retention), indicating a promising application of the mesoporous Ni-P nanocatalysts towards alkaline urea electrooxidation.
Journal: Electrochimica Acta - Volume 222, 20 December 2016, Pages 455-462