کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472894 1424138 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of Li7P3S11 glass-ceramic electrolyte by dissolution-evaporation method for all-solid-state lithium ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Preparation of Li7P3S11 glass-ceramic electrolyte by dissolution-evaporation method for all-solid-state lithium ion batteries
چکیده انگلیسی

Design/fabrication of solid state electrolytes with high ionic conductivity is of great importance to develop next-generation Li ion batteries. In this work, the Li7P3S11 glass-ceramic electrolyte is successfully synthesized by dissolution- evaporation approach. The solvent effect on the electrochemical performance of Li7P3S11 is investigated by electrochemical impedance spectroscopy and chronoamperometry tests. The Li7P3S11 electrolyte prepared by a solution of acetonitrile has a high ionic conductivity of 9.7 × 10−4 S cm−1 at 298 K and a low activation energy of 31.2 kJ mol−1. Impressively, a wide and stable electrochemical window up to 5 V (vs. Li/Li+) is demonstrated between the solid electrolyte and lithium electrode. The developed dissolution-evaporation approach shows good industrial prospect due to its advantages of energy conservation and high efficiency.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 219, 20 November 2016, Pages 235-240
نویسندگان
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