کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6473023 | 1424138 | 2016 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical Catalysis In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical Catalysis](/preview/png/6473023.png)
Efficient charge transport is a key to the successful design of electrocatalyst. In this work, we report the in-situ growth of ultrathin MOF material (ZIF-67) nanosheets on conductive Ti@TiO2/CdS substrate for high-efficient electrochemical catalysis due to optimized charge transport. The ultrathin ZIF-67 nanosheets were grown on Ti@TiO2/CdS nanowire array substrates resulting unique 3D hierarchical structures, which were investigated as electrocatalyst for the oxygen-evolution reaction (OER) and H2O2 oxidation. The nanowire-supported ZIF-67 nanosheet electrode shows remarkable electrocatalytic activity and excellent stability toward OER and H2O2 oxidation, which can be explained by the rapid electron transport along the 1D Ti@TiO2/CdS nanowire to Ti substrates, large electrochemical active surface area and the rising valence state of Co ions induced by electronegative N atom in imidazole ligands. Compared with other MOFs catalysts, we obtained a very small Tafel slope (42 mV/dec) and a small overpotential (0.41 V) at 10 mA cmâ2 for OER. When used for H2O2 detection, the electrode gave a high sensitivity of 1214.3 μAmMâ1cmâ2, a wide linear range of 5 μM-14 mM and a low detection limit of 1.11 μM. This research suggests that the in-situ grown nanostructure of Ti@TiO2/CdS/ZIF-67 hold great promise for advanced electrocatalytic electrode in water oxidation and H2O2 detection.
Journal: Electrochimica Acta - Volume 219, 20 November 2016, Pages 623-629