کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
64732 48368 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Room temperature CO oxidation catalyzed by NiO particles on mesoporous SiO2 prepared via atomic layer deposition: Influence of pre-annealing temperature on catalytic activity
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Room temperature CO oxidation catalyzed by NiO particles on mesoporous SiO2 prepared via atomic layer deposition: Influence of pre-annealing temperature on catalytic activity
چکیده انگلیسی


• We prepared NiO nanoparticles on mesoporous SiO2 by atomic layer deposition (ALD).
• NiO nanoparticles on SiO2 maintained their size of less than 2 nm up to 600 °C.
• NiO/SiO2 annealed at 450 °C showed the highest catalytic activity and stability.

We prepared NiO nanoparticles on mesoporous SiO2 using atomic layer deposition and additionally annealed the prepared samples at four different temperatures (300–750 °C) under dry air. NiO nanoparticles had lateral sizes less than ∼2 nm up to 600 °C, whereas annealing at a higher temperature (750 °C) resulted in a significant agglomeration of NiO, with the formation of 30 nm-sized particles. Annealing at a higher temperature resulted in a reduction in carbon impurities in the annealing temperature range of 300–600 °C. Among the four samples annealed at different temperatures, the 450 °C-annealed sample showed the highest CO oxidation activity at room temperature. CO oxidation reactivity of this sample initially decreased with reaction time; however, the deactivation became less pronounced over time, with maintenance of 60% of the initial activity of this catalyst after 680 min. Furthermore, 450 °C-annealing of used catalyst resulted in full recovery of the initial CO oxidation reactivity. These results suggest that ALD followed by annealing is a promising strategy for the fabrication of highly efficient and stable catalysts consisting of nanoparticles incorporated in the mesopores of a high-surface area support.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 414, April 2016, Pages 87–93
نویسندگان
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