کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
64761 | 48370 | 2016 | 7 صفحه PDF | دانلود رایگان |
• Homogeneous catalytic isomerization of allylic-alcohols in presence of water.
• Ru complexes containing the open adamantane phosphine dmoPTA.
• Bi-heterometallic-Ru–M complexes (M = Co, Ni, Zn) containing dmoPTA.
• Water and pH influence on the catalytic isomerization of allylic-alcohols.
The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.
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Journal: Journal of Molecular Catalysis A: Chemical - Volume 411, January 2016, Pages 27–33