کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6476261 1425379 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Quantitative compositional analysis of Estonian shale oil using comprehensive two dimensional gas chromatography
ترجمه فارسی عنوان
تجزیه و تحلیل کمی ترکیب روغن زیتون با استفاده از کروماتوگرافی گاز جامع دو بعدی
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


- Polar × mid-polar column combination GC × GC improves separation of highly polar oxygen containing compounds
- Estonian pyrolysis shale oil contains 39 wt.% of oxygen containing compounds
- Carbon number ranges from C3 to C26, C< 21 account for 95 wt.% of the sample
- Olefins and cycloalkanes, with concentrations of 17.5 wt.% and 16.8 wt.% respectively, are the major chemical classes

An Estonian pyrolysis shale oil has been characterized using comprehensive two dimensional gas chromatography (GC × GC) coupled to a flame ionization detector (FID) and time of flight mass spectrometer (TOF-MS). Oxygen containing compounds were abundant and the following classes were identified: benzenediols, hydroxybenzofurans, phenols, ketones, and naphthols. The large peak overlap observed for oxygenates with the hydrocarbon matrix using a non-polar × polar column combination made identification and quantification difficult. A methodology based on the more selective separation using a polar × non-polar and polar × mid-polar column configurations was developed and tested. The obtained bidimensional resolution confirms that the method provides an improved separation of unsaturated hydrocarbons, mid-polar and even highly polar oxygen containing compounds. The use of an internal standard methodology allowed complete quantification of the pyrolysis shale oil both by carbon number and chemical class.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 167, 1 December 2017, Pages 241-249
نویسندگان
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