کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6501327 | 46431 | 2014 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photo-catalytic activity of titanium dioxide carbon nanotube nano-composites modified with silver and palladium nanoparticles
ترجمه فارسی عنوان
فعالیت نانو کامپوزیتی نانولوله کربن دی اکسید تیتانیوم اصلاح شده با نانوذرات نقره و پالادیوم
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
نانولوله های کربنی، دی اکسید تیتانیوم، متیلن آبی، نانوذرات نقره، نانوذرات پالادیوم، رسوب بخار شیمیایی فلزات آلی،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
چکیده انگلیسی
Photo-catalytic noble metallic and bimetallic nano-composites (Ag or Pd/-TiO2/CNT) were synthesized using a commercial source of multi-walled carbon nanotubes via a modified dry-mix metal-organic chemical vapour deposition method (MOCVD). The titania loading was varied from 10-40Â wt.%, and the optimum TiO2/CNT photo-catalyst was determined using methylene blue degradation as a model probe reaction. Furthermore, acid-treated nanotubes and non-acid treated nanotubes were compared as a substrate for the synthesis of various titania nano-composites, and it was found that the acid treatment decreased the photo-catalytic activity of the titania CNT nano-composites. The 20Â wt.% titania on CNT samples were then further modified with silver, palladium, and a combination of both metals using the MOCVD technique. It was found that the silver titania CNT nano-composites were the most effective photo-catalyst for the degradation of methylene blue. The deposition of 2% Ag on 20% TiO2/MWCNT resulted in 92% degradation of 50Â mg/L MB in 4Â h with 1Â g/L of photo-catalyst. Palladium had little effect in altering the photo-catalytic activity of the titania CNT nano-composites, and the combination of both metals suppressed the photo-catalytic activity of the titania CNT nano-composites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volumes 156â157, September 2014, Pages 273-283
Journal: Applied Catalysis B: Environmental - Volumes 156â157, September 2014, Pages 273-283
نویسندگان
Nomso Hintsho, Leslie Petrik, Alexander Nechaev, Salam Titinchi, Patrick Ndungu,