کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
65735 48401 2014 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxidative functionalization of alkanes under dioxygen in the presence of homogeneous noble metal catalysts
ترجمه فارسی عنوان
فعال سازی اکسید کننده آلکان ها در اثر دیاکسیدان در حضور کاتالیزورهای نجیب همگن فلزی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Oxidative functionalization of alkanes catalyzed by noble metal complexes.
• Mechanism of action for homogeneous catalysts and catalytic systems.
• Designing catalytic systems involving the activation of alkanes and dioxygen.
• Advantages and drawbacks of existing catalytic systems.
• Gas-phase reactions in high-boiling solvents in the presence of immobilized catalysts.

Basic approaches to design of catalytic systems for homogeneous oxidative functionalization of alkanes in the presence of noble metals are overviewed. Special attention was given to catalytic systems for oxidation of C1–C4 alkanes with dioxygen as a green oxidant and to methods for dioxygen activation with reducing agents. The mechanisms of the relevant reactions are considered.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 385, April 2014, Pages 160–174
نویسندگان
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