کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6580334 | 1422940 | 2018 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Atomic-layer-deposited TiO2-SnZnO/carbon nanofiber composite as a highly stable, flexible and freestanding anode material for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We demonstrate the synthesis of a highly stable, freestanding and flexible anode material for lithium-ion batteries created by depositing a conformal coating of TiO2 on a SnZnO/carbon nanofiber (CNF) composite using atomic layer deposition. The term SnZnO is used here because metallic Sn is observed in the SnZnO/CNF composites after annealing under argon gas. The elemental composition of the material was confirmed by energy-dispersive X-ray spectroscopy, while the oxidation states of the elements were determined by X-ray photoelectron spectroscopy. Cross-sectional transmission electron microscopy showed that the core regions of the composite nanofibers were almost uniformly covered by a TiO2 shell. The specific capacities of the TiO2-coated and uncoated samples at a high current density (5C) were 413 and 159â¯mAh·gâ1, respectively. An analysis of the surface morphology after cycling indicated that the stability of the solid electrolyte interface layer increased after the formation of the protective conformal TiO2 layer. As a result, no signs of anode degradation were observed even after 700 cycles at a current density of 5C. We attribute this exceptional stability to the buffering of the anode material by the protective coating during volumetric expansion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 338, 15 April 2018, Pages 72-81
Journal: Chemical Engineering Journal - Volume 338, 15 April 2018, Pages 72-81
نویسندگان
Bhavana Joshi, Edmund Samuel, Min-Woo Kim, Sera Park, Mark T. Swihart, Woo Young Yoon, Sam S. Yoon,