کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6583596 | 456359 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Plasma-catalysis of metal loaded SBA-15 for toluene removal: Comparison of continuously introduced and adsorption-discharge plasma system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Plasma-catalysis of metal loaded SBA-15 for toluene removal: Comparison of continuously introduced and adsorption-discharge plasma system Plasma-catalysis of metal loaded SBA-15 for toluene removal: Comparison of continuously introduced and adsorption-discharge plasma system](/preview/png/6583596.png)
چکیده انگلیسی
The destruction of low concentrations of toluene using two non-thermal plasma catalytic systems has been investigated in this study. Metals (Ag, Mn and AgMn) loaded SBA-15 catalysts were prepared by an impregnation method and further characterized by X-ray diffraction (XRD), N2 adsorption-desorption isotherm and H2-temperature-programmed reduction (H2-TPR). In our research, two types of plasma catalytic system, including continuously introduced and adsorption-discharge plasma system, were studied. The results showed that the loaded metals retained the highly ordered mesopore structure of SBA-15. The activities of as-prepared catalysts for the toluene conversion and carbon balance in both catalytic systems decreased in the following order: AgMn/SBA-15Â >Â Ag/SBA-15Â >Â Mn/SBA-15Â >Â SBA-15, which were consistent with the ozone decomposition activities. Compared to traditional continuously introduced plasma system, the adsorption-discharge plasma system slightly increased toluene conversion and significantly improved the carbon balance. The reaction intermediates and products in two plasma systems were detected by the GC-MS and in situ FT-IR analyses. The results showed that the types of organic byproducts detected in the adsorption-discharge system greatly decreased compared to continuously introduced system. Moreover, the different mechanisms of two systems were discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 283, 1 January 2016, Pages 276-284
Journal: Chemical Engineering Journal - Volume 283, 1 January 2016, Pages 276-284
نویسندگان
Xiaoxin Xu, Peitao Wang, Weicheng Xu, Junliang Wu, Limin Chen, Mingli Fu, Daiqi Ye,